电子吸收的光谱学

出版时间：1999-12  出版社：东南大学出版社  作者：Lalanne, J. R.; Servant, L.; Carmona, F.  页数：325  

内容概要

This book, a companion volume to Electronic Structure and Chemical Bonding (World Scientific, 1996), is concerned with the teaching of optical spectroscopies of electronic absorption. It is the culmination of about ten years of experience in the teaching of the subject and the training of students to become teachers in the physical sciences. 　　The book covers topics of current research and includes about 30 problems with solutions, most of which are adapted from tests proposed recently at the "Aggregation" in chemistry and physics. It provides as much coverage of elementary quantum mechanics, group theory and the electronic structure of molecules as is necessary for the reader to understand the rest of the topics. Also included are numerous appendices, often presented as charts to facilitate assimilation, as well as short bibliographies, limited to basic books and review articles. 　　This volume will be an invaluable guide for teachers and potential teachers in the physical sciences, and more generally for students and engineers in chemical physics and physics.

书籍目录

PrefaceAcknowledgmentsSymbolsPART I Theoretical FrameChapter I.-  IntroductionChapter II. - Classical Theory of Light  II. 1.  Introduction: The different representations of light  II.2.  Classical theory of light　　II.2.1.  Electromagnetism and Maxwell's equations  　　　II.2.1.1.  Maxwell's equations　　　II.2.1.2.  The wave equation　　II.2.2.  Three solutions for Maxwell's equations  　　　II.2.2.1.  The spherical wave　　　II.2.2.2.  The plane wave　　　II.2.2.3.  Gaussian wave  　II.3.  Exercises and problems　　II. 3.1.  Electromagnetic wave propagation in vacuum　　II.3.2.  Search for a particular Gaussian solution of the wave equation　　II.3.3.  Treatment of Gaussian wm,es with lenses　II.4.  Appendices  　　II.4.1.  Table of electromagnetic waves  　　II. 4.2.  Various forms of the Maxwell's equations　　]1.4.3.  Three particular solutions to the wave equation  　II.5. BibliographyChapter HI- Matter and its properties　III. 1. Non relativistic quantum mechanics　　III.1.1. Fundamental principles and brief history　　　III. 1.1.1. Probabilistic description  　　　III. 1.1.2. The problem of measurement and operators　　III.1.2. Principles of the non relativistic quantum theory　　　III.l.2.1. Postulates concerning the description of the system　　　 III. 1.2.2. Principles for the measurement of physical quantities　　　 III. 1.2.3. Evolution principle　　　 III.1.2.4. Correspondence principle　　　 III.1.2.5. Spin creation principle　　　 III. 1.2.6. Antisymmetrization principle　III.2. Symmetry and group theory  　　 III. 2.1. Symmetry elements and svmmsetry operations　　 III.2.2. Representation of an operation by an operator　　 III.2.3. Group structure and classification　　 III.2.4. Group representation　　　 III.2.4.1. Introduction to the notion of representation　　　 III.2.4.2. Representation properties　　　 III.2.4.3. Direct product of two representations　III.3.  Application of quantum mechanics and group theory to the description of stationary electronic states in atoms and molecules　　 III.3.1. Description of the electronic structure of the hydrogen atom and of the　hydrogenic atoms　　　 III. 3.1.1. Solution of tile eigenvalue equation for tile Hamiltonian operator　　　 IlI.3.1.2, Energy and shell model　　　 III.3.1.3. State vector and atomic orbital multiplicity　　　 III.3.1.4. Various representations of probability densities in real space　　　 III.3.1.5. Spin orbit coupling　　 III.3.2. The description of the electronic structure of many-electron atoms　　    III.3.2.1. Central field approximation        III.3.2.2. Electrostatic and magnetic interactions: Russel-Saunders and spin-orbit couplings        III.3.2.3. Description of configurations　　　　III.3.3.Description of electronic structure of molecules　　　　III.3.3.1. General presentation　　　　Ill.3.3.2. Methods for solving the electronic eigenvalue equation　　 III.3.4. Vibrational and rotational structure of electronic levels in atoms　and molecules　　　 IlI.3.4.1. Vibrational structure　　　 III.3.4.2. Rotational structure　　　 III.3.4.3. Vibration-rotation interaction　　III.3.5. Conclusions and consequences about electronic levels　IlI.4. Exercises et problems　　III.4.1. Questions about symmetry: true or false?　　III.4.2. General aspects of LCAO theory　　III.4.3. Study of the orbitals of 1, 3 butadiene　　III.4.4. Energy ofsinglet and triplet states of a two-electron system　III.5. Appendices　　III.5.1. Main properties of linear transformations and matrices　　III.5.2. Representation of an operator by a matrix　　III.5.3. Tables of the postulates of quantum theory　　III.5. 4.  Tables of characters of the symmetry groups used in this book　III.6. Bibliography……PART II Optical Spectroscopies of Electronec AbsorptionINDEX