有机合成中的现代方法

出版时间：2004-11  出版社：世界图书出版公司  作者：W.Carruthers  页数：526  
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内容概要

有机合成中的现代方法，ISBN：9787506272506，作者：（ ）W.Carruthers著

书籍目录

Preface to the first editionPreface to the third edition1　Formation of carbon-carbon single bonds  1.1. Alkylation: importance of enolate anions  1.2. Alkylation of relatively acidic methylene groups  1.3. y-Alkylation of 1,3-dicarbonyl compounds; dianions in synthesis  1.4. Alkylation of ketones  1.5. The enamine and related reactions  1.6. Alkylation of a-thio and a-seleno carbanions  1.7. Umpolung (dipole inversion)  1.8. The aldol reaction  1.9. Allylic alkylation of alkenes  1.10. The dihydro-l,3-oxazine synthesis of aldehydes and ketones  1.11. Coupling of organonickel and organocopper com- plexes  1.12. Reactions of lithium organocuprates: copper-cata-lysed reactions of Grignard reagents  1.13. Synthetic applications of carbenes and carbenoids  1.14. Formation of carbon-carbon bonds by addition of free radicals to alkenes  1.15. Some photocyclisation reactions2  Formation of carbon--carbon double bonds  2.1. β-Elimination reactions  2.2. Pyrolytic syn eliminations  2.3. Sulphoxide-sulphenate rearrangement; synthesis of allyl alcohols  2.4. The Wittig and related reactions  2.5. Alkenes from sulphones  2.6. Decarboxylation of　β-lactones  2.7. Stereoselective synthesis of tri- and tetra- substituted alkenes  2.8. Fragmentation reactions  2.9. Oxidative decarboxylation of carboxylic acids  2.10. Alkenes from arylsuiphonylhydrazones  2.11. Stereospecific synthesis from 1,2-diols  2.12. Claisen rearrangement of allyl vinyl ethers  2.13. Reductive dimerisation of carbonyl compounds3  The Diels-Alder and related reactions  3.1. General  3.2. The dienophile - heterodienophiles, oxygen as a dienophile  3.3. The diene - acyclic dienes, heterodienes, 1,2-dimethylenecycloalkanes, vinylcycloalkenes and vinylarenes, aromatic hydrocarbons, cyclic dienes, cyclopentadienones and ortho-quinones, furans  3.4. Intramolecular Diels-Alder reactions  3.5. The retro Diels-Alder reaction  3.6. Catalysis by Lewis acids  3.7. Regiochemistry of the Diels-AIder reaction  3.8. "Stereochemistry of the Diels-Alder reaction  3.9. Asymmetric Diels-Alder reactions  3.10. Mechanism of the Diels-Aider reaction  3.11. Photosensitised Diels-Alder reactions  3.12. The erie reaction  3.13. Cyclo-addition reactions with allyl cations and allyl anions  3.14. 1,3-Dipolar cyclo-addition reactions4  Reactions at uaactivated C--H bonds  4.1. The Hoffmann-Loeffler-Freytag reaction  4.2. Cyclisation reactions of nitrenes  4.3. The Barton reaction and related processes - photoly-sis of organic nitrites and hypohalites, photolysis of N-nitrosoamides  4.4. Reaction of monohydric alcohols with lead tetra-acetate  4.5. Miscellaneous reactions - unsaturated alcohols from hydroperoxides, cyclobutanols by photolysis of ketones, long-range functionalisation of unacti-vated carbons on the steroid nucleus5  Cynthetic applications of organoboranes and organosilanes6  Oxidation7  ReductionReferencesIndex