出版时间:2003-6 出版社:世界图书出版公司(此信息作废) 作者:P..Flory 页数:672
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内容概要
《高分子化学原理(英文版)》由世界图书出版公司出版,内容包括: HISTORICAL INTRODUCTl0N、TYPES 0F POLYMERIC SUBSTANCES:DEFINITIONS AND 、MOLECULAR SIZE AND CHEMICAL REACTIVITY;PRINCIPLES OF CONDENSATION POLYMERIZATION、POLYMERIZATION OF UNSATURATED MONOMERS BY FREE RADICAL MECHANISMS、COPOLYMERIZATION,EMULSION POLYMERIZATION AND IONIC POLYMERIZATION、THE STRUCTURE OF VINYL POLYMERS等。
书籍目录
PrefaceCHAPTER Ⅰ HISTORICAL INTRODUCTl0N 1.Early Investigations on NaturaUy Occurring Polymers 2.Early Encounters with Condensation Polymers 3.Vinyl Polymers 4.Rise of the Macromoleoular Hypothesis References.CHAPTER Ⅱ TYPES 0F POLYMERIC SUBSTANCES:DEFINITIONS AND CLASSIFICATIONS 1.Primary Definitions 2.Classification of Polymers 3.Condensation Polymers and Condensation Polymerization 4.Addition Pobrmers from Unsaturated Monomers 5.Polymerization of Cyclic Compounds 6.Anomalous Conden8ation Polymerizations 7.Inorganic Polymers 8.Concluding Remarks on the Structure and Properties of High Polymers References.CHAPTER Ⅲ MOLECULAR SIZE AND CHEMICAL REACTIVITY;PRINCIPLES OF CONDENSATION POLYMERIZATION 1.Chemical Reactivity in Homologous Series of Monomeric Com—pouuds 2.Theory of the Reactivity of Large Molecules 3.Kinetics of Condensation Polymerization 4.Kinetics of Degradation of Condensation Polymers 4a.Hydrolysis of Cellulose and Cellulose Derivatives 4b.Hydrolysis of Polyamides 4c.Alcoholysis of Polyesters 4d.Interchange Reactions in Condensation Polymers 5.Molecular Weights of Linear Condensation Polymers 6.Ring Formation vs.Chain Polymerization 7.Summary and Conclusions: The Principle of Equal Reactivity of All Functional Groups References.CHAPTER Ⅳ POLYMERIZATION OF UNSATURATED MONOMERS BY FREE RADICAL MECHANISMS 1.The Conversion of Monomer to Polymer 1a.Kinetic Scheme for Polymerization in the Presence of an Initiator 1b.Dependence of Initial Rates on the Concentrations of Initi-ator and Monomer 1c.Initiator Efficiencies 1d.Evaluation of Parameters 1e.The Course of the Conversion of Monomer to Polymer;Autoacceleration 1f.Kinetics of Thermal Polymerization 2.Chain Lengths 2a.Kinetic Chain Length and Degree of Polymerization 2b.Kinetics of Chain Transfer. 2c.Chain Transfer in Undiluted Monomer; Evaluation of Parameters 2d.Chain Transfer with Solvents 2e.Dependence of the Degree of Polymerization on Tempera-ture 2f.Regulators 3.Absolute Values of the Rate Constants for Individual Steps 3a.Methods for Determining the Mean Lifetime of an Active Center. 3b.Experimental Results 4.Inhibition and Retardation of Polymerization 4a.Reaction Mechanisms 4b.Kinetics of Inhibition and Retardation 4c.Allylic Polymerization; Autoinhibition References.CHAPTER Ⅴ COPOLYMERIZATION,EMULSION POLYMERIZATION AND IONIC POLYMERIZATIONCHAPTER Ⅵ THE STRUCTURE OF VINYL POLYMERSCHAPTER Ⅶ DETERMINATION OF MOLECULAR WEIGHTSCHAPTER Ⅷ MOLECULAR WEIGHT DISTRIBUTIONS IN LINEAR POLYMERSCHAPTER Ⅸ MOLECULAR WEIGHT DISTRIBUTIONS IN NONLINEARCHAPTER Ⅹ CONFIGTURATION OF POLYMER CHAINSCHAPTER Ⅺ RUBBER ELASTICITYCHAPTER Ⅻ STATISTICAL THERMODYNAMICS OF POLYMER SOLUTIONSCHAPTER XIII PHASE EQUILIBRIA IN POLYMER SYSTEMSCHAPTER XIV CONFIGURATIONAL AND FRICTIONAL PROPERTIES OF THE POLYMER MOLECULE IN DILUTE SOLUTIONGLOSSARY OF PRINCIPAL SYMBOLSAUTHOR INDEX SUBJECT INDEX
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