高分子物理

出版时间：2012-4  出版社：机械工业出版社  作者：斯特罗伯  页数：518  
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内容概要

　　《高分子物理：“结构与性能”背后的概念(英文版.原书第3版)》对高分子物理的多个领域作了生动而详细的介绍，内容涵盖链构象，高分子溶液，共混物和嵌段共聚物，半晶态聚合物，聚合物网络，聚合物流体等多种体系。作者还使用了大量的数学处理与实验结果，对提出的机理与数学模型进行示例与验证，勾勒出一幅浓墨重彩的高分子物理画卷。
　　《高分子物理：“结构与性能”背后的概念(英文版.原书第3版)》可作为化学化工、材料科学和物理学等专业的本科生和研究生教材，也可供有关领域的专家、学者阅读参考。

作者简介

作者:(德)G.斯特罗伯

书籍目录

出版说明
推荐序
preface（前言）
preface to the first edition/第1版前言
1constitution and architecture of chains/链的组成与构造1
2single chain conformations /单链构象15
2.1rotational isomeric states /旋转异构态15
2.2helices/螺旋19
2.3coils /线团22
2.3.1the ideal chain/理想链26
2.3.2the expanded chain/膨胀链45
2.4the persistent chain/持续链55
2.5the ising chain/ 伊辛链59
3polymer solutions /聚合物溶液69
3.1dilute and semidilute solutions/稀溶液与半稀溶液70
3.1.1osmotic pressure/渗透压71
3.2screening of excluded volume forces/排除体积力的屏蔽82
3.3polyelectrolyte solutions/聚电解质溶液89
3.3.1condensation and screening of charges /电荷的团聚与屏蔽89
3.3.2chain stretching, salt effects and interchain
ordering/链伸展、盐效应与链间序95
3.3.3osmotic pressure/渗透压100
4polymer blends and block copolymers/共混物与嵌段共聚物105
4.1the flory?huggins treatment of polymer
mixtures/聚合物混合物的flory?huggins处理方法106
4.1.1phase diagrams: upper and lower miscibility
gap/相图：上临界与下临界混溶间隙117
4.2phase separation mechanisms/相分离机理122
4.3critical fluctuations and spinodal
decomposition/临界涨落与旋节线分解129
4.3.1critical scattering/临界散射132
4.3.2decomposition kinetics/分解动力学143
4.4block copolymer phases/嵌段共聚物的相结构151
4.4.1layered structures/层状结构155
4.4.2pretransitional phenomena/前转变现象157
5the semicrystalline state/半结晶态165
5.1structure characteristics/结构特征167
5.1.1morphological elements /基本形态167
5.1.2structure parameters/结构参数173
5.2kinetics of crystallization and melting/结晶与熔融动力学181
5.3laws for the structure development/结构变化规律190
5.3.1the multistage model/多阶段模型199
5.4mechanisms of secondary crystallization/二级结晶机理205
5.4.1the insertion mode/插层模式208
5.4.2surface crystallization and melting/表面结晶与熔融212
5.5crystallization from oriented melts/取向熔体结晶216
6mechanical and dielectric response/力学与介电响应223
6.1response functions/响应函数224
6.1.1viscoelasticity/粘弹性224
6.1.2orientational polarization/取向极化228
6.1.3general relationships/通用公式229
contents6.2relaxatory modes/松弛模式236
6.2.1single?time relaxation process/单时间松弛过程237
6.2.2retardation and relaxation time spectra/推迟与松弛时间242
6.3specific relaxation processes and flow behavior/具体松弛过程与流动行为
245
6.3.1local processes/局部过程246
6.3.2glass?rubber transition and melt flow/玻璃?橡胶转变与熔体流动250
6.3.3the glass transition temperature/玻璃化转变温度269
6.3.4relaxation in partially crystalline systems/半晶体系中的松弛277
7conjugated polymers/共轭聚合物287
7.1electrooptic activity/光电活性289
7.1.1excitons and free charges/激发与自由电荷289
7.1.2electroluminescence/电发光297
7.2effects of doping/掺杂效应302
7.2.1electrical conductivity/电导率302
7.2.2magnetism and reflectivity/磁性与反射率306
8microscopic dynamics/微观运动学313
8.1the fluctuation?dissipation theorem/涨落?耗散原理313
8.2the rouse model/rouse模型317
8.2.1stress relaxation/应力松弛325
8.2.2the dielectric normal mode /介电基准模式330
8.3entanglement effects in polymer melts/聚合物熔体中的缠结效应333
8.3.1the reptation model/爬行模型338
8.4solution viscosities/溶液粘度 343
8.4.1neutral polymers: hydrodynamic
interaction/中性聚合物：流体力学作用344
8.4.2polyelectrolytes: coulomb interaction/聚电解质：静电作用 352
9non?linear mechanics /非线性力学357
9.1rubber elasticity/橡胶弹性361
9.1.1the fixed junction model of ideal rubbers/理想橡胶的固定结点模型364
9.1.2the cauchy strain tensor/ cauchy应变张量371
9.1.3finger?s constitutive equation/ finger本构方程376
9.2swelling of neutral and electrolytic gels/中性与电解质凝胶的溶胀384
9.3non?newtonian melt flow/非牛顿熔体的流动390
9.3.1rheological material functions /流变材料函数391
9.3.2the lodge liquid/ lodge液体398
9.3.3the stress?optical rule/应力?光学规则404
10deformation, yielding and fracture/形变、屈服与断裂415
10.1shear deformation in semicrystalline
polymers/半晶聚合物中的剪切形变418
10.1.1critical strains/临界应变418
10.1.2constituents of the drawing stress/拉伸应力的成分426
10.1.3the mechanics of neck formation/细颈形成机理429
10.1.4fibrillar state of order/纤维化有序态435
10.2crazing/银纹 444
10.3brittle fracture/脆性断裂450
10.3.1linear fracture mechanics /线性断裂力学453
10.3.2the slow mode of crack growth/裂缝生长的缓慢模式455
ascattering experiments/散射实验463
a.1fundamentals/基本概念463
a.1.1basic equations/基本方程464
a.1.2time?resolved scattering experiments/时间分解的散射实验468
a.2absolute intensities/绝对强度471
a.3low angle scattering properties/小角散射性质474
a.3.1guinier?s law/ guinier公式474
a.3.2forward scattering/前散射476
a.4special polymer systems/特种聚合物体系477
a.4.1binary mixtures and block copolymers/二元混合物与嵌段共聚物477
a.4.2two?phase layer systems/两相层状体系484
bglossary of symbols/术语与符号493
cbibliography/参考书目501
references/参考文献505
index/索引

章节摘录

版权页：   插图：   Polymers，also known as macromolecules，are built up of a large number of molecular units that are linked together by covalent bonds．Usually they represent orgamc compoundg，containing carbon atoms together with hydrogen，oxygen，nitrogen，and halogens，etc．In this first chapter，we briefly survey the main characteristics of their chemical constitution and molecular architecture and introduce the notions employed for their description．using examples for the explanation． All these polymers are electrically neutral． If chains are built up of monomers that contain an ionizable group， i．e．， a group that can dissociate into a chain—fixed kation or anion and a mobile counter—ion bearing the opposite charge， a polyelectrolyte is obtained． Table 1．2 collects a few typical examples． The first three compounds are synthetic polymers， the other two samples are biopolymers； cellulose and starch in the form of derivatives which include ionizable substitutes．  Charges on a chain can also be created by doping processes． For conjugated polymers， i．e．， chains with conjugated C—C double bonds， this is particularly easy． Even more importantly， the produced charges are mobileand thus provide electrical conductivity． Table 1．3 compiles some of these special materials．

编辑推荐

《时代教育•国外高校优秀教材精选•高分子物理:"结构与性能"背后的概念(英文版 原书第3版)》以英文原版的形式出版，原汁原味地呈现给广大作者，无疑为高分子界的广大读者做了一件好事。《时代教育•国外高校优秀教材精选•高分子物理:"结构与性能"背后的概念(英文版 原书第3版)》可作为化学化工、材料科学和物理学等专业的本科生和研究生相关课程的教材和参考书，也可供相关领域的专家、学者阅读参考。

用户评论 (总计7条)

•   高分子物理经典书籍，英文版的不错
•   很好的关于构性关系的书籍
•   真的很好 比一般的高物要深刻
•   老外写的书，简单易懂，很不错！
•   封面有稍许摩擦折旧
•   需要慢慢翻译，可以用来作为参考书籍，理论知识丰富而且精辟！
•   G.Strobl是名誉世界的实验高分子物理学家，对理论的理解非常深刻，曾任欧洲高分子物理学会主席，地位可见一斑，这本书是作者毕生所学之大成，是个人所见对高分子物理叙述最为精辟的一本入门教材，要比国内教材深的多，事实上这才是真正的高分子物理，而非简单的写写画画，指指点点（国内所谓的高分子物理），建议初学者有比较好的数理基础，最好有四大力学的基础，再看此书，会对高分子物理有一种全新的认识和高度。作者是散射实验专家，因此具备散射基础再阅读此书无疑会大有裨益，散射方面的专著可以参看C.C.Han 2011年所著新书（只需看前两章即可）。但本书中参杂了许多作者自己的观念，例如在结晶中的metaphase state，即多阶段模型，颇受争议，同时力学性能中引入subcrystal也非常值得商榷，但无疑这会促进人们的思考，对推动学科的发展是非常有帮助的。这本书有中译本，南大胡文兵，应化所门永锋等人组织翻译的，翻译的不是特别理想（但还不错了），建议中英文对照看，比较好，因为中译本中有些许言语不像的地方，而英文版中也充斥着浓重的德国口音，两相对照，方有所获。