均相催化

出版时间：2008-3  出版社：科学出版社  作者：Piet W.N.M.Van Leeuwen  页数：407  字数：630000  
Tag标签：无  

内容概要

过渡金属化合物均相催化领城近年来发展非常迅速，工业界、学术界纷纷报道发现了众多的奇妙催化剂。本书基于作者在教学及工业实践方面广泛的经验，探讨了许多新的和旧的重要反应。每章均以基础知识开始，以最新的内容结束。本书侧重于概念，但也列举了许多实验室合成有机化学品的关键丁业流程和应用流程。全书涵盖精细化学品，大宗化学品，聚合物，高技术聚合物，药品，也包括重要的技巧和反应类型等。同时还介绍了一些反应过程方案、环境问题和安全问题。 本书可供催化专业高年级本科生、研究生以及研究人员参考使用。

书籍目录

PrefaceAcknowledgements1.  INTRODUCTION  1.1  CATALYSIS  1.2  HOMOGENEOUS CATALYSIS  1.3  HISTORICAL NOTES ON HOMOGENEOUS CATALYSIS  1.4  CHARACTERISATION OF THE CATALYST  1.5  LIGAND EFFECTS    1.5.1  Phosphines and phosphites: electronic effects    1.5.2  Phosphines and phosphites: steric effects    1.5.3  Linear Free Energy Relationships    1.5.4  Phosphines and phosphites: bite angle effects  1.6  LIGANDS ACCORDING TO DONOR ATOMS    1.6.1  Anionic and neutral hydrocarbyl groups    1.6.2  Alkoxy and imido groups as anionic ligands    1.6.3  Amines, imines, oxazolines and related ligands    1.6.4  Phosphines, phosphites, phosphorus amides, phospholes and related ligands    1.6.5  Carbenes, carbon monoxide    1.6.6  Common anions2.  ELEMENTARY STEPS  2.1  CREATION OF A "VACANT" SITE AND CO-ORDINATION OF THE SUBSTRATE  2.2  INSERTION VERSUS MIGRATION  2.3  β-ELIMINATION AND DE-INSERTION  2.4  OXIDATIVE ADDITION  2.5  REDUCTIVE ELIMINATION  2.6  α-ELIMINATION REACTIONS  2.7  CYCLOADDITION REACTIONS INVOLVING A METAL  2.8  ACTIVATION OF A  SUBSTRATE TOWARD NUCLEOPHILIC  ATTACK    2.8.1  Alkenes    2.8.2  Alkynes    2.8.3  Carbon monoxide    2.8.4  Other substrates  2.9  a-BOND METATHESIS  2.10  DIHYDROGEN ACTIVATION  2.11  ACTIVATION BY LEWIS ACIDS    2.11.1  Diels-Alder additions    2.11.2  Epoxidation    2.11.3  Ester condensation  2.12  CARBON-TO-PHOSPHORUS BOND BREAKING  2.13  CARBON-TO-SULFUR BOND BREAKING  2.14  RADICAL REACTIONS3. KINETICS  3.1  INTRODUCTION  3.2  TWO-STEP REACTION SCHEME  3.3  SIMPLIFICATIONS OF THE RATE EQUATION AND THE RATEDETERMINING STEP  3.4  DETERMINING THE SELECTIVITY  3.5  COLLECTION OF RATE DATA  3.6  IRREGULARITIES IN CATALYSIS4.  HYDROGENATION  4.1  WILKINSON'S CATALYST  4.2  ASYMMETRIC HYDROGENATION    4.2.1  Introduction    4.2.2  Cinnamic acid derivatives    4.2.3  Chloride versus weakly coordinating anions; alkylphosphines versus arylphosphines    4.2.4  Incubation times  4.3  OVERVIEW OF CHIRAL BIDENTATE LIGANDS    4.3.1  DUPHOS    4.3.2  BINAP catalysis    4.3.3  Chiral ferrocene based ligands  4.4  MONODENTATE LIGANDS  4.5  NON-LINEAR EFFECTS  4.6  HYDROGEN TRANSFER5.  ISOMERISATION  5.1  HYDROGEN SHIFTS  5.2  ASYMMETRIC ISOMERISATION  5.3  OXYGEN SHIFTS6.  CARBONYLATION OF METHANOL AND METHYL ACETATE  6.1  ACETIC ACID  6.2  PROCESS SCHEME MONSANTO PROCESS  6.3  ACETIC ANHYDRIDE  6.4  OTHER SYSTEMS    6.4.1  Higher alcohols    6.4.2  Phosphine-modified rhodium catalysts    6.4.3  Other metals7.  COBALT CATALYSED HYDROFORMYLATION  7.1  INTRODUCTION  7.2  THERMODYNAMICS  7.3  COBALT CATALYSED PROCESSES  7.4  COBALT CATALYSED PROCESSES FOR HIGHER ALKENES  7.5  KUHLMANN COBALT HYDROFORMYLATION PROCESS  7.6  PHOSPHINE MODIFIED COBALT CATALYSTS: THE SHELL PROCESS  7.7  COBALT CARBONYL PHOSPHINE COMPLEXES    7.7.1  Carbonyl species    7.7.2  Phosphine derivatives8.  RHODIUM CATALYSED HYDROFORMYLATION  8.1  INTRODUCTION  8.2  TRIPHENYLPHOSPHINE AS THE LIGAND   8.2.1  The mechanism    8.2.2  Ligand effects and kinetics    8.2.3  Regioselectivity    8.2.4  Process description, rhodium-tpp    8.2.5  Two-phase process, tppts: Ruhrchemie/Rhone-Poulenc    8.2.6  One-phase catalysis, two-phase separation  8.3  DIPHOSPHINES AS LIGANDS    8.3.1  Xantphos ligands: tuneable bite angles  8.4  PHOSPHITES AS LIGANDS    8.4.1  Electronic effects    8.4.2  Phosphites: steric effects  8.5  DIPHOSPHITES  8.6  ASYMMETRIC HYDROFORMYLATION    8.6.1  Rhodium catalysts: diphosphites    8.6.2  Rhodium catalysts: phosphine-phosphite ligands9.  ALKENE OLIGOMERISATION  9.1  INTRODUCTION  9.2  SHELL-HIGHER-OLEFINS-PROCESS    9.2.1  Oligomerisation    9.2.2  Separation    9.2.3  Purification, isomerisation, and metathesis    9.2.4  New catalysts  9.3  ETHENE TRIMERISATION  9.4  OTHER ALKENE OLIGOMERISATION REACTIONS10.  PROPENE POLYMERISATION  10.1  INTRODUCTION TO POLYMER CHEMISTRY    10.1.1  Introduction to Ziegler Natta polymerisation    10.1.2  History of homogeneous catalysts  10.2  MECHANISTIC INVESTIGATIONS    10.2.1  Chain-end control: syndiotactic polymers    10.2.2  Chain-end control: isotactic polymers  10.3  ANALYSIS BY13C NMR SPECTROSCOPY    10.3.1  Introduction    10.3.2  Chain-end control    10.3.3  Site control mechanism  10.4  THE DEVELOPMENT OF METALLOCENE CATALYSTS    10.4.1  Site control: isotactic polymers    10.4.2  Site control: syndiotactic polymers    10.4.3  Double stereoselection: chain-end and site control  10.5  AGOSTIC INTERACTIONS  10.6  THE EFFECT OF DIHYDROGEN  10.7  FURTHER WORK USING PROPENE AND OTHER ALKENES  10.8  NON-METALLOCENE ETM CATALYSTS  10.9  LATE TRANSITION METAL CATALYSTS11.  HYDROCYANATION OF ALKENES  11.1  THE ADIPONITRILE PROCESS  11.2  LIGAND EFFECTS 12.  PALLADIUM CATALYSED CARBONYLATIONS OF ALKENES  12.1  INTRODUCTION  12.2  POLYKETONE    12.2.1  Background and history    12.2.2  Elementary steps: initiation    12.2.3  Elementary steps: migration reactions    12.2.4  Elementary steps: chain termination, chain transfer    12.2.5  Elementary steps: ester formation as chain termination  12.3  LIGAND EFFECTS ON CHAIN LENGTH    12.3.1  Polymers    12.3.2  Ligand effects on chain length: Propanoate    12.3.3  Ligand effects on chain length: Oligomers  12.4  ETHENE/PROPENE/CO TERPOLYMERS  12.5  STEREOSELECTIVE STYRENE/CO COPOLYMERS13.  PALLADIUM CATALYSED CROSS-COUPLING REACTIONS  13.1  INTRODUCTION  13.2  ALLYLIC ALKYLATION  13.3  HECK REACTION  13.4  CROSS-COUPLING REACTION  13.5  HETEROATOM-CARBON BOND FORMATION  13.6  SUZUKI REACTION14.  EPOXIDATION  14.1  ETHENE AND PROPENE OXIDE  14.2  ASYMMETRIC EPOXIDATION    14.2.1  Introduction    14.2.2  Katsuki-Sharpless asymmetric epoxidation    14.2.3  The Jacobsen asymmetric epoxidation  14.3  ASYMMETRIC  HYDROXYLATION  OF  ALKENES  WITH  OSMIUM TETROXIDE    14.3.1  Stoichiometric reactions    14.3.2  Catalytic reactions  14.4  JACOBSEN ASYMMETRIC RING-OPENING OF EPOXIDES  14.5  EPOXIDATIONS WITH DIOXYGEN 15. OXIDATION WITH DIOXYGEN  15.1  INTRODUCTION  15.2  THE WACKIER REACTION  15.3  WACKIER TYPE REACTIONS  15.4  TEREPHTHALIC ACID  15.5  PPO 16.  ALKENE METATHESIS  16.1  INTRODUCTION  16.2  THE MECHANISM  16.3  REACTION OVERVIEW  16.4  WELL-CHARACTERISED  TUNGSTEN  AND  MOLYBDENUM CATALYSTS  16.5  RUTHENIUM CATALYSTS  16.6  STEREOCHEMISTRY  16.7  CATALYST DECOMPOSITION  16.8  ALKYNES  16.9  INDUSTRIAL APPLICATIONS17.  ENANTIOSELECTIVE CYCLOPROPANATION  17.1  INTRODUCTION  17.2  COPPER CATALYSTS  17.3  RHODIUM CATALYSTS    17.3.1  Introduction    17.3.2  Examples of rhodium catalysts18. HYDROSILYLATION  18.1  INTRODUCTION  18.2  PLATINUM CATALYSTS  18.3  ASYMMETRIC PALLADIUM CATALYSTS  18.4  RHODIUM CATALYSTS FOR ASYMMETRIC KETONE REDUCTION19.  C-H FUNCTIONALISATION  19.1  INTRODUCTION  19.2  ELECTRON-RICH METALS  19.3  HYDROGEN TRANSFER REACTIONS OF ALKANES  19.4  BORYLATION OF ALKANES  19.5  THE MURAI REACTION  19.6  CATALYTIC a-BOND METATHESIS  19.7  ELECTROPHILIC CATALYSTSSUBJECT INDEX

用户评论 (总计2条)

•   这本书还是不错的，老外的书不错
•   书不错，印刷也还可以，不过包装还要改进，书装订的地方容易裂开